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Two-Phase Hydroformylation of Octene-1 with Rhodium Complexes of P[C6H4(CH2)mC6H4-p-SO3Na]3 (m = 3, 6). Rate and Selectivity Enhancement with Surface-Active Phosphines

✍ Scribed by Ding, Hao; Hanson, Brian E.; Bartik, Tamas; Bartik, Berit


Book ID
126206748
Publisher
American Chemical Society
Year
1994
Tongue
English
Weight
384 KB
Volume
13
Category
Article
ISSN
0276-7333

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Surface active phosphines for catalysis
✍ TamΓ‘s Bartik; Hao Ding; Berit Bartik; Brian E. Hanson πŸ“‚ Article πŸ“… 1995 πŸ› Elsevier Science 🌐 English βš– 604 KB

The novel optically active phosphine, bis( 8-phenyloctyl) (Menth)phosphine, (Menth = lR,3R,4S( -)menthyl) is synthesized and sulfonated under mild conditions to yield the corresponding sulfonated phosphine, disodium bis-( 8-(pura-sulfonatophenyl)octyl) (Menth)phosphine. The water soluble phosphine