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Synthesis of Cationic Iridium(I) Complexes of Water-Soluble Phosphine Ligands, [Ir(CO)(TPPMS) 3 ]CF 3 SO 3 , [Ir(CO)(H 2 O)(TPPTS) 2 ]CF 3 SO 3 , and [Ir(CO) 2 (TPPMS) 3 ]ClO 4 (TPPMS = PPh 2 ( m -C 6 H 4 SO 3 K), TPPTS = P( m -C 6 H 4 SO 3 Na) 3 )

✍ Scribed by Paterniti, David P.; Francisco, Laura W.; Atwood, Jim D.


Book ID
120543674
Publisher
American Chemical Society
Year
1999
Tongue
English
Weight
108 KB
Volume
18
Category
Article
ISSN
0276-7333

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Aqueous Organometallic Chemistry. Synthe
✍ GΓ‘bor Papp; Henrietta HorvΓ‘th; Ágnes KathΓ³; Ferenc JoΓ³ πŸ“‚ Article πŸ“… 2005 πŸ› John Wiley and Sons 🌐 German βš– 98 KB

## Abstract An improved procedure for the preparation of the known H~2~O‐soluble hydrogenation and hydroformylation catalyst, [RuH(Cl)(CO)(__m__tppms)~3~] (__m__tppms=__meta__‐monosulfonated triphenylphosphine) was developed. In contrast to the methods reported earlier, this synthesis yields the co

Carbonylation of Iridium(I) and Iridium(