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Mono-Sulfonated Derivatives of Triphenylphosphine, [NH 4 ]TPPMS and M(TPPMS) 2 (TPPMS = P(Ph) 2 ( m -C 6 H 4 SO −3 ); M = Mn 2+ , Fe 2+ , Co 2+ and Ni 2+ ). Crystal Structure Determinations for [NH 4 ][TPPMS]·½H 2 O, [Fe(H 2 O) 5 (TPPMS)]TPPMS, [Co(H 2 O) 5 TPPMS]TPPMS and [Ni(H 2 O) 6 ](TPPMS) 4 ·H 2 O

✍ Scribed by Barton, Mark R.; Zhang, Yuegang; Atwood, Jim D.


Book ID
120878353
Publisher
Taylor and Francis Group
Year
2002
Tongue
English
Weight
460 KB
Volume
55
Category
Article
ISSN
0095-8972

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Aqueous biphasic catalytic hydrogenation
✍ Pablo J. Baricelli; Tirza Ascanio; Eduardo Lujano; Luis G. Melean; Margarita Bor 📂 Article 📅 2007 🏛 Elsevier Science 🌐 English ⚖ 258 KB

The hydrosoluble complex [Rh(-Pz)(CO)(TPPMS)] 2 , Pz = pyrazolate ligand, and TPPMS = (C 6 H 5 ) 2 P(C 6 H 4 SO 3 Na) was used as catalytic precursor in the two phase hydrogenation reaction of the individual olefins (1-hexene, styrene, cyclohexene and 2,3-dimethyl-1-butene) to give the main expected