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Two novel heterometallic CuII-SrII coordination polymers based on 3,5-pyrazoledicarboxylic acid: synthesis, crystal structures and magnetic properties

✍ Scribed by Chen, Yanmei; Zheng, Lina; She, Shixiong; Chen, Zhou; Hu, Bin; Li, Yahong

Book ID
120025503
Publisher
Royal Society of Chemistry
Year
2011
Tongue
English
Weight
706 KB
Volume
40
Category
Article
ISSN
1477-9226

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Two new 4d-4f Ln-Ag heterometallic coordination polymers, {[Ln 3 Ag 5 (IN) 10 (H 2 O) 7 ] Á 4(ClO 4 ) Á 4(H 2 O)} n (Ln ¼ Eu (1) and Sm (2), HIN ¼ isonicotinic acid), have been synthesized under hydrothermal conditions by reactions of Ln 2 O 3 , AgNO 3 , HIN and HClO 4 , and characterized by element