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Two new 2p–3d–4f heterometallic coordination polymers based on 3,5-pyrazoledicarboxylic acid: synthesis, crystal structures and magnetic properties

✍ Scribed by Wang, Yan; Li, Xing-Xing; Jiang, Huan; Xia, Bo-Wen; Deng, Ning; Zhu, Yan-Wu; Jin, Guan-Ping; Ni, Xiao-Min; He, Jian-Bo


Book ID
121335569
Publisher
Elsevier Science
Year
2013
Tongue
English
Weight
451 KB
Volume
35
Category
Article
ISSN
1387-7003

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Two new 4d-4f Ln-Ag heterometallic coordination polymers, {[Ln 3 Ag 5 (IN) 10 (H 2 O) 7 ] Á 4(ClO 4 ) Á 4(H 2 O)} n (Ln ¼ Eu (1) and Sm (2), HIN ¼ isonicotinic acid), have been synthesized under hydrothermal conditions by reactions of Ln 2 O 3 , AgNO 3 , HIN and HClO 4 , and characterized by element