Two new lanthanide complexes of isonicotinic acid N-oxide (HL), namely [Ln(L) 2 (H 2 O) 4 ] n AE(NO 3 ) n AEn(H 2 O) for Ln = Sm or Tb, have been synthesized and characterized by spectroscopic and crystallographic methods. IR spectra suggest that isonicotinic acid N-oxide acts as a O,O 0 -bidentate
β¦ LIBER β¦
Two new scorpionates vanadium haloperoxidases model complexes: Synthesis and structure of VO(O2)(pzH)(HB(pz)3) and VO(O2)(pzH)(B(pz)4) (pzH = pyrazole(C3H4N2))
β Scribed by Yongheng Xing; Yuanhong Zhang; Zheng Sun; Ling Ye; Yongting Xu; Maofa Ge; Baoli Zhang; Shuyun Niu
- Book ID
- 108174970
- Publisher
- Elsevier Science
- Year
- 2007
- Tongue
- English
- Weight
- 612 KB
- Volume
- 101
- Category
- Article
- ISSN
- 0162-0134
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The Schiff base ligand {3-hydroxyl-5-(hydroxymethyl)-2-methylpyridine-4-yl-methylene}benzohydrazide hydrochloride monohydrated {(hhmmbH)ClΓH 2 O} (1) was prepared by reaction of pyridoxine hydrochloride with benzoic acid hydrazide. The reaction of 1 with [VO(acac) 2 ] and triethylamine yields the ne