Two New Iron(II) Spin-Crossover Complexes with N4O2 Coordination Sphere and Spin Transition around Room Temperature
✍ Scribed by Birgit Weber; Jaroslava Obel; Dunie Henner-Vásquez; Wolfgang Bauer
- Publisher
- John Wiley and Sons
- Year
- 2009
- Tongue
- English
- Weight
- 645 KB
- Volume
- 2009
- Category
- Article
- ISSN
- 1434-1948
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## Abstract This paper reports the synthesis of a family of mononuclear complexes [Fe(L)]X~2~ (X=BF~4~, PF~6~, ClO~4~) with hexadentate ligands L=Hpy‐DAPP ({bis[__N__‐(2‐pyridylmethyl)‐3‐aminopropyl](2‐pyridylmethyl)amine}), Hpy‐EPPA ({[__N__‐(2‐pyridylmethyl)‐3‐aminopropyl][__N__‐(2‐pyridylmethyl)
The new Fe[ SNO,-sal-N( 1,4,7, IO)] spin-crossover complex'has been investigated by Miissbauer spectroscopy, magnetic susceptibility measurements, and X-ray diffraction powder studies as a function of temperature. The spin conversion occurs in two steps separated by a 30" broad spin equilibrium doma