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Two New Iron(II) Spin-Crossover Complexes with N4O2 Coordination Sphere and Spin Transition around Room Temperature

✍ Scribed by Birgit Weber; Jaroslava Obel; Dunie Henner-Vásquez; Wolfgang Bauer


Publisher
John Wiley and Sons
Year
2009
Tongue
English
Weight
645 KB
Volume
2009
Category
Article
ISSN
1434-1948

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📜 SIMILAR VOLUMES


Spin Crossover in a Family of Iron(II) C
✍ Galina S. Matouzenko; Serguei A. Borshch; Erwann Jeanneau; Mark B. Bushuev 📂 Article 📅 2008 🏛 John Wiley and Sons 🌐 English ⚖ 460 KB 👁 2 views

## Abstract This paper reports the synthesis of a family of mononuclear complexes [Fe(L)]X~2~ (X=BF~4~, PF~6~, ClO~4~) with hexadentate ligands L=Hpy‐DAPP ({bis[__N__‐(2‐pyridylmethyl)‐3‐aminopropyl](2‐pyridylmethyl)amine}), Hpy‐EPPA ({[__N__‐(2‐pyridylmethyl)‐3‐aminopropyl][__N__‐(2‐pyridylmethyl)

Fe[5NO2-sal-N(1,4,7,10)]: a new iron(II)
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The new Fe[ SNO,-sal-N( 1,4,7, IO)] spin-crossover complex'has been investigated by Miissbauer spectroscopy, magnetic susceptibility measurements, and X-ray diffraction powder studies as a function of temperature. The spin conversion occurs in two steps separated by a 30" broad spin equilibrium doma