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Two New Iridoid Glycosides from Hedyotis tenelliflora Blume

✍ Scribed by Jing-Feng Zhao; Qin-Mei Yuan; Xiao-Dong Yang; Hong-Bing Zhang; Liang Li


Publisher
John Wiley and Sons
Year
2005
Tongue
German
Weight
63 KB
Volume
88
Category
Article
ISSN
0018-019X

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✦ Synopsis


Abstract

Two new iridoid glycosides, teneoside A (=(2a__R__,5__S__)‐5‐[(β‐D‐glucopyranosyl)oxy]‐2a,4a,5,7b‐tetrahydro‐4‐{[(α‐L‐rhamnopyranosyl)oxy]methyl}‐1__H__‐2,6‐dioxacyclopenta[cd]inden‐1‐one; 1) and teneoside B (=methyl (1__S__,5__R__)‐1‐[(β‐D‐glucopyranosyl)oxy]‐1,4a,5,7a‐tetrahydro‐5‐hydroxy‐7‐{[(α‐L‐rhamnopyranosyl)oxy]methyl}cyclopenta[c]pyran‐4‐carboxylate; 2), were isolated from the roots of Hedyotis tenelliflora Blume, along with two known compounds, deacetylasperuloside (3) and scandoside methyl ester (4). Their structures were elucidated by chemical methods (acid hydrolysis) and spectroscopic analyses.


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