The Chemical Investigation of Genus Hedyotis. Part 5. Iridoids from Hedyotis hedyotidea. -The isolation and identification of two new iridoids, the asperulosic acid derivative (I) and asperuloside (II) from Hedyotis hedyotidea is described.
New Anthraquinone and Iridoid Glycosides from the Stems of Hedyotis hedyotidea
โ Scribed by Xiao-Ping Hu; Shu-Wei Zhang; Shan-Shan Liu; Li-Jiang Xuan
- Publisher
- John Wiley and Sons
- Year
- 2011
- Tongue
- German
- Weight
- 232 KB
- Volume
- 94
- Category
- Article
- ISSN
- 0018-019X
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โฆ Synopsis
Abstract
Five new anthraquinone glycosides, hedanthrosides AโE (1โ5, resp.) and two new iridoid glycosides, hediridosides A and B (6 and 7, resp.), along with two known anthraquinones and four known iridoids, were isolated from the stems of Hedyotis hedyotidea (DC.) Merr. The structures of the new compounds were elucidated on the basis of 1Dโ and 2DโNMR, and HRโMS analysis and chemical methods.
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## Abstract Two new iridoid glycosides, teneoside A (=(2a__R__,5__S__)โ5โ[(__ฮฒ__โDโglucopyranosyl)oxy]โ2a,4a,5,7bโtetrahydroโ4โ{[(__ฮฑ__โLโrhamnopyranosyl)oxy]methyl}โ1__H__โ2,6โdioxacyclopenta[__cd__]indenโ1โone; **1**) and teneoside B (=methyl (1__S__,5__R__)โ1โ[(__ฮฒ__โDโglucopyranosyl)oxy]โ1,4a,5
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