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Two methods for generation of aroyl(quinoxalin-2-yl)ketene

✍ Scribed by P. S. Silaichev, A. N. Maslivets


Book ID
115525041
Publisher
SP MAIK Nauka/Interperiodica
Year
2012
Tongue
English
Weight
160 KB
Volume
48
Category
Article
ISSN
1070-4280

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Chemistry of ketene acetals IV. A simple
✍ R. W. Aben; R. Hofstraat; J. W. Scheeren 📂 Article 📅 2010 🏛 Elsevier Science 🌐 English ⚖ 494 KB

## Abstract α‐Acyloxy aldehydes (**2a,b**) react with 1,1‐dimethoxypropene (**1**) in the presence of ZnCl~2~ to yield 2,2‐dimethoxy‐3‐methyloxetanes (**3a,b**). Stronger electron‐withdraxing acyl groups are necessary for the analogous conversion ofα‐acyloxy ketones (**2c,d,e**). Hydrolysis of the