## Abstract The addition of difluorocarbene to bicyclo[2.2.2]octa‐2,5‐diene gave the __exo__ and __endo__ 1:1 cyclopropane adducts. In contrast to norbornadiene, no __homo__‐1,4 adduct was formed. The adducts were thermally stable under the conditions of their formation and separation (<170°). Howe
✦ LIBER ✦
Two iron–tricarbonyl complexes with substituted bicyclo[2.2.2]octadienes
✍ Scribed by Irngartinger, H. ;Oeser, T. ;Köhler, C. M.
- Book ID
- 114509593
- Publisher
- International Union of Crystallography
- Year
- 1993
- Tongue
- English
- Weight
- 418 KB
- Volume
- 49
- Category
- Article
- ISSN
- 0108-2701
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The I-dimethoxymethyl-5,6-dimethylidene-7-oxabicyclo[2.2. I jhept-2-ene (9) has been prepared. On treatment with Fe,(CO),, the endocyclic double bond C(2)=C(3) was coordinated first giving the Corresponding exo-Fe(C0)4 complex 10. The latter reacted with Fe,(CO), and afforded cis-heptacarbonyl-p -[(