Ring-opening metathesis polymerization of substituted bicyclo[2.2.2]octadienes: a new precursor route to poly(1,4-phenylenevinylene)
โ Scribed by Conticello, Vincent P.; Gin, Douglas L.; Grubbs, Robert H.
- Book ID
- 127332368
- Publisher
- American Chemical Society
- Year
- 1992
- Tongue
- English
- Weight
- 412 KB
- Volume
- 114
- Category
- Article
- ISSN
- 0002-7863
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๐ SIMILAR VOLUMES
R)-(+)-7-0x~rhicyclo/2.2.I]hr~~t-5-mr-r.~o-2-carboxylic ucid(ZR), which cun bc tmnsformvd into CNrb~)hydr~~tltP-.~ub,~~iINtYd monomer 5 uppropriate ji,r ring opening metr~thesis polymerizution (ROMP) was preporud by on mzymlitic kinetic rrsolutinn of7oxrrbicycb[2.2.1]hrpt-5-rnr-~xo-2-cc~rhoxylic NCi
A new class of ruthenium based catalysts coordinated with a 1,3-dimesityl-4,5-dihydroimidazol-2-ylidene and a Schiff base ligand have been tested in ring-closing metathesis and ring-opening metathesis polymerization reactions. The results obtained point out that the synergy of Schiff base ligands wi