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Two Diorganopotassates: Crystal Structure of [K(C6H6)][K{C(SiMe3)2(SiMe2Ph)}2]

✍ Scribed by Prof. Colin Eaborn; Dr. Peter B. Hitchcock; Dr. Keith Izod; Dr. J. David Smith

Publisher: John Wiley and Sons
Year: 1996
Tongue: English
Weight: 292 KB
Volume: 34
Category: Article
ISSN: 0044-8249
DOI: 10.1002/anie.199526791

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✦ Synopsis

3a-BF4 To a wlution of I-BF, (0.46g. 1 mmol) in dichloromethane (5 mL) at ~ 50 c' wiis added palladium tetrakis(tripheny1phosphane) (0.86 g. 0 75 mmolj. After \tirriiig for 1X h a t 40 C. the solvent was removed in vacuo. and the reziduc w a \ washed several times with toluene andether to give 3a-BF, as i i y c l l o ~. powder (25% yield); m.p. 175-176°C; "P NMR (CDCI,).

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