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Crystallographic report: 1,4-Bis(triphenylstannylmethyldimethylsilyl)benzene, p-(Ph3SnCH2SiMe2)2C6H4

✍ Scribed by Dainis Dakternieks; Bernhard Zobel; Edward R. T. Tiekink

Publisher
John Wiley and Sons
Year
2003
Tongue
English
Weight
93 KB
Volume
17
Category
Article
ISSN
0268-2605

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The dinuclear molecule of p-{[(Me 3 Si) 2 CH]Sn(Cl) 2 CH 2 SiMe 2 } 2 C 6 H 4 is centrosymmetric and adopts an `S' conformation that is stabilized by intramolecular CÐHÁÁÁp interactions. The tin atom exists within a distorted tetrahedron defined by a C 2 Cl 2 donor set.

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## Abstract Each tin atom of the title compound is five‐coordinate, defined by 2C, 2Cl and 1O atoms, and shows a distorted square pyramidal configuration stabilized by intramolecular SnΒ· Β· Β·O or SnΒ· Β· Β·Cl interactions. Both nitrate anions coordinate the tin atoms in a monodentate mode. Copyright Β©