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Two-Dimensional Metal−Organic Frameworks: A System with Competing Chelating Ligands

✍ Scribed by Keene, Tony D.; Hursthouse, Michael B.; Price, Daniel J.

Book ID
125897059
Publisher
American Chemical Society
Year
2009
Tongue
English
Weight
999 KB
Volume
9
Category
Article
ISSN
1528-7483

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## Abstract Reaction of a pyridinecarboxylate ligand with copper salt affords a novel coordinative polymer [Cu(bpdc)(H~2~O)~2~·2H~2~O]n (bpdc=.2,2'‐bipyridyl‐3,3'‐dicarboxylate). It has 2‐D (4,4) layered network extended by the tetradentate bridging ligands, further interestingly, the coordinative