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Synthesis of a two-dimensional porous framework based on symmetrical organic ligand and linking metal ion

✍ Scribed by Jian Wu

Publisher
John Wiley and Sons
Year
2009
Tongue
English
Weight
225 KB
Volume
44
Category
Article
ISSN
0232-1300

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✦ Synopsis

Abstract

Reaction of a pyridinecarboxylate ligand with copper salt affords a novel coordinative polymer [Cu(bpdc)(H~2~O)~2~·2H~2~O]n (bpdc=.2,2'‐bipyridyl‐3,3'‐dicarboxylate). It has 2‐D (4,4) layered network extended by the tetradentate bridging ligands, further interestingly, the coordinative and lattice water molecules acting as donor and acceptor linking the uncoordinated carboxylate groups into a inorganic (6,3) network. (© 2009 WILEY‐VCH Verlag GmbH & Co. KGaA, Weinheim)

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A Novel Three-Dimensional Metal-Organic Framework Constructed from Two-Dimensional Interpenetrating Layers Based on Trinuclear Cobalt Clusters: [Co3(btec)(C2O4)(H2O)2]n
✍ Yang-Guang Li; Na Hao; En-Bo Wang; Ying Lu; Chang-Wen Hu; Lin Xu 📂 Article 📅 2003 🏛 John Wiley and Sons 🌐 English ⚖ 202 KB

## Abstract A novel coordination polymer [Co~3~(btec)(C~2~O~4~)(H~2~O)~2~]~__n__~ (1; btec = 1,2,4,5‐benzenetetracarboxylate) has been hydrothermally synthesized and characterized by IR, XPS, XRPD, TG analysis and single‐crystal X‐ray diffraction. The structural analysis reveals that 1 exhibits a n