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Two Active Sites for Photocatalytic Oxidation of Formic Acid on TiO2: Effects of H2O and Temperature

✍ Scribed by Darrin S. Muggli; Michael J. Backes

Book ID: 112256856
Publisher: Elsevier Science
Year: 2002
Tongue: English
Weight: 222 KB
Volume: 209
Category: Article
ISSN: 0021-9517
DOI: 10.1006/jcat.2002.3640

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## Abstract On the surface: Adsorption of O~2~ at the surface oxygen vacancy (SOV) sites of TiO~2~ reconstructs the lattice oxygen (healing SOVs), resulting in a decrease of the photocatalytic activity of oxidizing CO over vacuum‐pretreated TiO~2~ with increasing temperature (see scheme). Adsorptio