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Active sites and effects of H2O and temperature on the photocatalytic oxidation of 13C-acetic acid on TiO2

✍ Scribed by Michael J. Backes; Adrienne C. Lukaski; Darrin S. Muggli

Book ID
113459912
Publisher
Elsevier Science
Year
2005
Tongue
English
Weight
913 KB
Volume
61
Category
Article
ISSN
0926-3373

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## Abstract On the surface: Adsorption of O~2~ at the surface oxygen vacancy (SOV) sites of TiO~2~ reconstructs the lattice oxygen (healing SOVs), resulting in a decrease of the photocatalytic activity of oxidizing CO over vacuum‐pretreated TiO~2~ with increasing temperature (see scheme). Adsorptio