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Two 2-D 36 tessellated metal–organic frameworks constructed from trimetallic clusters and dicarboxylate ditopic links

✍ Scribed by Jianghua He; Yuetao Zhang; Jihong Yu; Qinhe Pan; Ruren Xu

Book ID: 118485943
Publisher: Elsevier Science
Year: 2006
Tongue: English
Weight: 669 KB
Volume: 41
Category: Article
ISSN: 0025-5408
DOI: 10.1016/j.materresbull.2006.01.018

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## Abstract Hydrothermal reactions of CdCl~2~·2.5H~2~O or ZnCl~2~, sodium dicyanamide, and sodium azide yield two interesting photoluminescent coordination polymers, namely, [Cd{Cd~3~(μ~3~‐OH)(dcadtzH)~3~(H~2~O)~6~}~2~] (1) and [Zn~5~(μ~3~‐OH)~2~(μ‐OH)~2~(dcadtz)~2~]·2H~2~O (2) [dcadtzH~3~ = bis(5‐