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Two isostructural 3D metal–organic frameworks constructed from 1D [H2Mo4O14]n2n− chains and the flexible bis-pyridyl-bis-amide ligand

✍ Scribed by Lin, Hongyan; Xu, Chuang; Wang, Xiuli; Chang, Zhihan; Tian, Aixiang; Liu, Guocheng; Zhang, Juwen


Book ID
122972032
Publisher
Elsevier Science
Year
2013
Tongue
English
Weight
997 KB
Volume
36
Category
Article
ISSN
1387-7003

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## Abstract Hydrothermal reactions of CdCl~2~·2.5H~2~O or ZnCl~2~, sodium dicyanamide, and sodium azide yield two interesting photoluminescent coordination polymers, namely, [Cd{Cd~3~(μ~3~‐OH)(dcadtzH)~3~(H~2~O)~6~}~2~] (1) and [Zn~5~(μ~3~‐OH)~2~(μ‐OH)~2~(dcadtz)~2~]·2H~2~O (2) [dcadtzH~3~ = bis(5‐