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Tuning the self-assembly of lanthanide triple stranded heterobimetallic helicates by ligand design

✍ Scribed by Jensen, Thomas B. ;Scopelliti, Rosario ;Bünzli, Jean-Claude G.

Book ID
121505646
Publisher
Royal Society of Chemistry
Year
2008
Tongue
English
Weight
471 KB
Volume
8
Category
Article
ISSN
1477-9226

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## Abstract Unsymmetrical substituted bidentate benzimidazol‐2‐ylpyridine ligands L2 and L3 react with [Ru(dmso)~4~Cl~2~] in ethanol to give statistical 1:3 mixtures of __fac__‐[Ru(L__i__)~3~]^2+^ and __mer__‐[Ru(L__i__)~3~]^2+^ (__i__=2, 3; Δ__G__⊖~isomerisation~=−2.7 kJ mol^−1^). In more polar so