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Lanthanide Triple-Stranded Helicates: Controlling the Yield of the Heterobimetallic Species

✍ Scribed by Jensen, Thomas B.; Scopelliti, Rosario; Bünzli, Jean-Claude G.


Book ID
121477976
Publisher
American Chemical Society
Year
2006
Tongue
English
Weight
270 KB
Volume
45
Category
Article
ISSN
0020-1669

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The structure of triple-stranded G·2C po
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The thermal stability of a new polynucleotide complex has been used to establish the hydrogen-bonding structure of three-stranded C-G-CH+ helices. In the Hoogsteen structure, the 8NH2 group of 8NH2GMP can form a third hydrogen bond to the CH+ strand, but in the alternative structure, the 8NHz group