Tuning the Decomposition Temperature in Complex Hydrides: Synthesis of a Mixed Alkali Metal Borohydride
✍ Scribed by E. Anne Nickels; Martin Owen Jones; William I. F. David; Simon R. Johnson; Rebecca L. Lowton; Marco Sommariva; Peter P. Edwards
- Publisher
- John Wiley and Sons
- Year
- 2008
- Tongue
- English
- Weight
- 387 KB
- Volume
- 120
- Category
- Article
- ISSN
- 0044-8249
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## Abstract The η^4^‐diphosphacyclobutadiene complexes [M(η^5^‐C~5~R~5~)(η^4^‐P~2~C~2~Bu)] (M Co, Rh; R H, Me), react with Rh(I), Pt(O), and Pt(II) centers via the phosphorus lone paris of the rings of afford mixed metal complexes. The crystal and molecular structure of the novel hexarhodium co