Tuning Photophysical and Electrochemical Properties of Cationic Iridium(III) Complex Salts with Imidazolyl Substituents by Proton and Anions
โ Scribed by Zhao, Qiang; Liu, Shujuan; Shi, Mei; Li, Fuyou; Jing, Hao; Yi, Tao; Huang, Chunhui
- Book ID
- 125805995
- Publisher
- American Chemical Society
- Year
- 2007
- Tongue
- English
- Weight
- 463 KB
- Volume
- 26
- Category
- Article
- ISSN
- 0276-7333
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## Abstract We report the synthesis, characterisation, photophysical and electrochemical properties of a series of cationic cyclometallated Ir^III^ complexes of general formula [Ir(ppy)~2~(phen)]PF~6~ (ppy=2โphenylpyridine, phen=a substituted phenanthroline). A feature of these complexes is that th
## Abstract A series of cationic diiminoiridium(III) complexes [Ir(ppyโ__N__,__C__)~2~(Lโ__N__,__N__)](PF~6~) has been prepared [Hppy = 2โphenylpyridine; L = 4,4โฒโ__t__Bu~2~dpbpy (1), 4,4โฒโMe~2~dpbpy (2), 4,4โฒโMe~2~pbpy (3), 4,4โฒโMe~2~bpy (4)] and their photophysical and electrochemical properties