## Abstract This manuscript reports the synthesis and photophysical investigation of a series of Ir^III^ complexes Ir(__C__∧__N__)~2~(__O__∧__O__) which are functionalized in the __para__ position of the pyridine ring by styryl groups substituted with electron‐donor and ‐acceptor end groups. The sa
Iridium(III) Complexes with Sulfonyl and Fluorine Substituents: Synthesis, Stereochemistry and Effect of Functionalisation on their Photophysical Properties
✍ Scribed by Roberta Ragni; Enrico Orselli; Gregg S. Kottas; Omar Hassan Omar; Francesco Babudri; Adriana Pedone; Francesco Naso; Gianluca M. Farinola; Luisa De Cola
- Publisher
- John Wiley and Sons
- Year
- 2009
- Tongue
- English
- Weight
- 541 KB
- Volume
- 15
- Category
- Article
- ISSN
- 0947-6539
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## Abstract We report the synthesis, characterisation, photophysical and electrochemical properties of a series of cationic cyclometallated Ir^III^ complexes of general formula [Ir(ppy)~2~(phen)]PF~6~ (ppy=2‐phenylpyridine, phen=a substituted phenanthroline). A feature of these complexes is that th
## Abstract A series of cationic diiminoiridium(III) complexes [Ir(ppy‐__N__,__C__)~2~(L‐__N__,__N__)](PF~6~) has been prepared [Hppy = 2‐phenylpyridine; L = 4,4′‐__t__Bu~2~dpbpy (1), 4,4′‐Me~2~dpbpy (2), 4,4′‐Me~2~pbpy (3), 4,4′‐Me~2~bpy (4)] and their photophysical and electrochemical properties