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A comparison of cis- and trans-cobalt(III) complexes with phosphorus and arsenic ligands; the effect of stereochemistry on redox and spectroscopic properties

✍ Scribed by William Levason; Stephen R. Preece; Christopher S. Frampton


Publisher
Elsevier Science
Year
1996
Tongue
English
Weight
425 KB
Volume
15
Category
Article
ISSN
0277-5387

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## Abstract Rate constants for the hydrolysis (__k__~h~) of six different amines in __trans‐__[Co((BA)~2~en)(amine)~2~]ClO~4~ complexes (amine = aniline 1a, para‐toluidine 1b, benzylamine 1c (primary amines), pyrrolidine 2a, piperidine 2b, morpholine 2c (secondary amines), and (BA)~2~en = Bisbenzoy