Benzyne reacts more rapidly with electron-rich alkenes than electron-deficient alkenes, a result of the abnormally low energy LUMO of benzyne, which results from the acetylene bending enforced by the benzyne geometry.
Tuning of the Electronic Properties of a Cyclopentadienylruthenium Catalyst to Match Racemization of Electron-Rich and Electron-Deficient Alcohols
✍ Scribed by Oscar Verho; Eric V. Johnston; Erik Karlsson; Jan-E. Bäckvall
- Publisher
- John Wiley and Sons
- Year
- 2011
- Tongue
- English
- Weight
- 578 KB
- Volume
- 17
- Category
- Article
- ISSN
- 0947-6539
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