Tungstate-catalyzed oxidation of tetrahydroquinolines with hydrogen peroxide: A novel method for the synthesis of cyclic hydroxamic acids
β Scribed by Murahashi, Shunichi; Oda, Tetsuya; Sugahara, Toshiaki; Masui, Yoshiyuki
- Book ID
- 120230287
- Publisher
- American Chemical Society
- Year
- 1990
- Tongue
- English
- Weight
- 825 KB
- Volume
- 55
- Category
- Article
- ISSN
- 0022-3263
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π SIMILAR VOLUMES
## Ir(I)(coe) 2 Cl] 2 (2 mol%)-catalyzed hydrogen peroxide oxidation of hydroxamic acids in the presence of cyclopentadiene gave the corresponding cycloadducts up to 97% yield. With a catalyst loading of 0.05 mol%, a maximum TON was attained to 740.
## Abstract It was found that __tert__βBuNH~2~ is an efficient catalyst for epoxidation of __Ξ±__,__Ξ²__βunsaturated ketones with 30% H~2~O~2~ under mild conditions. For most of the cyclic unsaturated ketones used, moderate to excellent yields (45%β93%) were obtained within 24 h period.