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Tungstate-catalysed oxidation of tetrahydroquinolines with hydrogen peroxide: a novel method for synthesis of cyclic hydroxamic acids

✍ Scribed by Murahashi, Shun-Ichi; Oda, Tetsuya; Sugahara, Toshiaki; Masui, Yoshiyuki

Book ID
120388255
Publisher
The Royal Society of Chemistry
Year
1987
Tongue
English
Weight
158 KB
Volume
19
Category
Article
ISSN
0022-4936

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## Abstract It was found that __tert__‐BuNH~2~ is an efficient catalyst for epoxidation of __Ξ±__,__Ξ²__‐unsaturated ketones with 30% H~2~O~2~ under mild conditions. For most of the cyclic unsaturated ketones used, moderate to excellent yields (45%–93%) were obtained within 24 h period.