## Abstract Precise values for the ratio of the Larmor frequencies, __w__~1H~/__w__~2H~, were measured at constant field for various organic compounds. The values of the Larmor frequency ratio depend on carbon‐hydrogen bond hybridization. The best ratio for the ghost referencing of ^2^H NMR spectra
Tritium nuclear magnetic resonance spectroscopy—I: Technique, internal referencing and some preliminary results
✍ Scribed by J. Bloxsidge; J. A. Elvidge; J. R. Jones; E. A. Evans
- Publisher
- John Wiley and Sons
- Year
- 1971
- Tongue
- English
- Weight
- 673 KB
- Volume
- 3
- Category
- Article
- ISSN
- 0749-1581
No coin nor oath required. For personal study only.
✦ Synopsis
Abstract
Routine measurement of triton magnetic resonance spectra is described for the first time, using a micro‐bulb sample tube assembly to obviate radiological hazards. Levels of isotope abundance and chemical concentration, the problem of self‐radiolysis and the general usefulness of the technique are discussed. Results are given for a selection of compounds including glucose, amino‐acids, thymidine and uridine. The self‐radiolysis of the last is followed.
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