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Tris(O,O′-di­methyl­di­thio­phosphato)­chromium(III)

✍ Scribed by Ito, Tetsuzo

Publisher
International Union of Crystallography
Year
2002
Tongue
English
Weight
181 KB
Volume
58
Category
Article
ISSN
1600-5368

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✦ Synopsis

The title complex molecule, [Cr(C 2 H 6 O 2 PS 2 ) 3 ], has a twofold rotation axis passing through the Cr atom and a P atom. The Cr atom is coordinated by six S atoms in a distorted octahedral arrangement. The CrÐS bond distances are in the range 2.420 (2)±2.441 (5) A Ê , with an average of 2.429 (7) A Ê .

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Tris(O-methyl­di­thio­carbonato)­chromiu
Tris(O-methyl­di­thio­carbonato)­chromium(III)
✍ Ito, Tetsuzo 📂 Article 📅 2002 🏛 International Union of Crystallography 🌐 English ⚖ 186 KB

In the title complex, [Cr(C 2 H 3 OS 2 ) 3 ], the Cr atom is coordinated by six S atoms in a distorted octahedral arrangement. The six CrÐS bond distances are in the range 2.391 (1)±2.406 (1) A Ê , with an average of 2.397 (2) A Ê .

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✍ Ito, Tetsuzo 📂 Article 📅 2003 🏛 International Union of Crystallography 🌐 English ⚖ 148 KB

In the title complex, [Co(C 2 H 3 OS 2 ) 3 ], the Co atom is coordinated by six S atoms in a distorted octahedral arrangement. The six CoÐS bond distances are in the range 2.262 (1)±2.275 (1) A Ê , with an average of 2.270 (2) A Ê .

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Linear-chain bis(μ-O,O′-di­methyl di­thio­phosphato)­lead(II)
✍ Ito, Tetsuzo ;Maeda, Yoshinori 📂 Article 📅 2004 🏛 International Union of Crystallography 🌐 English ⚖ 177 KB

Single-crystal X-ray study T = 296 K Mean '(O±C) = 0.012 A Ê R factor = 0.029 wR factor = 0.028 Data-to-parameter ratio = 13.4 For details of how these key indicators were automatically derived from the article, see http://journals.iucr.org/e.