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Trisodium yttrium(III) hexachloride

โœ Scribed by Liao, Wuping ;Dronskowski, Richard

Book ID
104481971
Publisher
International Union of Crystallography
Year
2004
Tongue
English
Weight
228 KB
Volume
60
Category
Article
ISSN
1600-5368

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โœฆ Synopsis

Colourless single crystals of Na 3 YCl 6 , crystallizing in the cryolite structure type and isotypic with Na 3 GdCl 6 -II and Na 3 MCl 6 (M = Sc, DyยฑLu), were prepared from a ยฏux of YCl 3 , NaCN and NaN 3 ; the trivalent yttrium is octahedrally coordinated by chlorine atoms with an average YรCl distance of 2.62 A รŠ . The Y atom and one Na atom lie on centres of symmetry.

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