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Trisodium heptaphosphide in reactions with alkyl and aryl tosylates

✍ Scribed by V. A. Milyukov; A. V. Kataev; E. Hey-Hawkins; O. G. Sinyashin

Book ID
106520392
Publisher
Springer
Year
2007
Tongue
English
Weight
385 KB
Volume
56
Category
Article
ISSN
1573-9171

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πŸ“œ SIMILAR VOLUMES

Trisodium heptaphosphide in reactions wi
Trisodium heptaphosphide in reactions with cyclopropenyl complexes of nickel
✍ V. A. Milyukov; A. V. Kataev; E. Hey-Hawkins; O. G. Sinyashin πŸ“‚ Article πŸ“… 2007 πŸ› Springer 🌐 English βš– 268 KB

Reactions of trisodium heptaphosphide with half sandwich cyclopropenyl complexes of nickel gave sodium 1,2 diphosphacyclopentadienide. The influence of the ligand environment of the nickel atom on the formation of sodium 1,2 diphosphacyclopentadienide was studied.

Zirconocene-catalyzed alkylation of aryl
Zirconocene-catalyzed alkylation of aryl alkenes with alkyl tosylates, sulfates and bromides
✍ Jun Terao; Tsunenori Watanabe; Koyu Saito; Nobuaki Kambe; Noboru Sonoda πŸ“‚ Article πŸ“… 1998 πŸ› Elsevier Science 🌐 French βš– 232 KB

Styrenes were alkylated with alkyl tosylates, sulfates and bromides in the presence of a zirconocene catalyst and "BuMgC1 in THF. By the use of this reaction, primary and secondary alkyl groups can be introduced regioselectively at the benzylic carbon of styrenes to give a-substituted ethylbenzenes.