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Tris(N,N-disubstituted-dithiocarbamato)manganese(IV) and -cobalt(IV) tetrafluoroborates

✍ Scribed by Saleh, Ramzi Y.; Straub, Darel K.

Book ID
120203550
Publisher
American Chemical Society
Year
1974
Tongue
English
Weight
410 KB
Volume
13
Category
Article
ISSN
0020-1669

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Low-spin d4 complexes with formulae [Fe&C.NR& j %Fz exhl%it magnetically perturbed Miissbauer spectra at 4.2 K which are consistent with the ljresence of singJet electronic ground states. These Carl arise by spin-orbit coupling in second order. Magnetic susceptibili;;y measurements support the MBssb