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Tris(imidodiphosphinato) Cationic Complexes of Silicon, Germanium, and Tin

✍ Scribed by Dr. A. Schmidpeter; Dipl.-Chem. K. Stoll


Publisher
John Wiley and Sons
Year
1968
Tongue
English
Weight
260 KB
Volume
7
Category
Article
ISSN
0044-8249

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Bis(amidinate) Complexes of Silicon and
✍ Hans H. Karsch; Peter A. SchlΓΌter; Manfred Reisky πŸ“‚ Article πŸ“… 1998 πŸ› John Wiley and Sons 🌐 English βš– 380 KB πŸ‘ 1 views

The synthesis of novel bis(amidinate) silicon and germanium complexes is described. The reaction of two equiv. of [MeC(NiPr) 2 ]Li β€’ THF (1) with SiCl 4 , GeCl 4 or GeCl 2 β€’dioxane affords [MeC(NiPr) 2 ] 2 SiCl 2 (2), [MeC(NiPr) 2 ] 2 GeCl 2 (3) and