Bis(amidinate) Complexes of Silicon and Germanium

✍ Scribed by Hans H. Karsch; Peter A. Schlüter; Manfred Reisky

• Publisher: John Wiley and Sons
• Year: 1998
• Tongue: English
• Weight: 380 KB
• Volume: 1998
• Category: Article
• ISSN: 1434-1948
• DOI: 10.1002/(sici)1099-0682(199804)1998:4<433::aid-ejic433>3.0.co;2-p

✦ Synopsis

The synthesis of novel bis(amidinate) silicon and germanium complexes is described. The reaction of two equiv. of [MeC(NiPr) 2 ]Li • THF (1) with SiCl 4 , GeCl 4 or GeCl 2 •dioxane affords [MeC(NiPr) 2 ] 2 SiCl 2 (2), [MeC(NiPr) 2 ] 2 GeCl 2 (3) and