Tris(ethylenediamine-κ2N,N′)nickel(II) naphthalene-2,6-disulfonate monohydrate
✍ Scribed by Huo, Li-Hua ;Gao, Shan ;Lu, Zhen-Zhong ;Xu, Shi-Xiao ;Zhao, Hui
- Publisher
- International Union of Crystallography
- Year
- 2004
- Tongue
- English
- Weight
- 313 KB
- Volume
- 60
- Category
- Article
- ISSN
- 1600-5368
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The title complex, [Zn(C 2 H 8 N 2 ) 3 ][Zn(C 4 N 2 S 2 ) 2 ], exists as discrete ions, both of which lie on twofold rotation axes. The [Zn(C 2 H 8 N 2 ) 3 ] 2+ cation exhibits a slightly distorted octahedral geometry. In the [Zn(C 4 N 2 S 2 ) 2 ] 2À anion, the Zn II atom is surrounded by two chelat
In the title complex, [Cd(C 2 H 8 N 2 ) 3 ][Cu(C 4 N 2 S 2 ) 2 ], the Cd II atom has a distorted octahedral geometry. The Cu II atom is in a distorted square-planar geometry. Both ions lie on twofold rotation axes. They are not connected covalently.
The title compound, [CuCl 2 (C 11 H 24 N 2 )], crystallizes as fourcoordinate monomers with distorted square-planar geometry. The complex is chiral and forms racemic crystals. Molecules which have an S-con®guration at nitrogen have a !conformation of the ®ve-membered chelate ring, and those with R-c