Tris(4-fluoro-2,2'-bipyridyl)iron(II) hexafluorophosphate
✍ Scribed by Cho, C. K. ;Secco, A. S.
- Book ID
- 114508764
- Publisher
- International Union of Crystallography
- Year
- 1992
- Tongue
- English
- Weight
- 327 KB
- Volume
- 48
- Category
- Article
- ISSN
- 0108-2701
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📜 SIMILAR VOLUMES
Single-crystal X-ray study T = 293 K Mean '(C±C) = 0.006 A Ê R factor = 0.052 wR factor = 0.153 Data-to-parameter ratio = 12.9 For details of how these key indicators were automatically derived from the article, see http://journals.iucr.org/e.
The title compound, [Fe(C 10 H 8 N 2 ) 3 ][FeCl 4 ] 2 , consists of a pseudo-octahedral tris(2,2 H -bipyridyl)iron(II) cation and two pseudo-tetrahedral tetrachloroferrate(III) anions.
Tris(5,5 0 0 0 -dimethyl-2,2 0 0 0 -bipyridyl-j 2 N,N 0 0 0 )iron(II) bis(perchlorate) 5,5 0 0 0 -dimethyl-2,2 0 0 0 -bipyridyl solvate
The title compound, [Cu(C~10~H~8~N~2~)~3~](PF~6~)~2~, is a six-coordinate copper(II) complex with a slightly tetragonally elongated octahedral coordination geometry. There are weak C—H...F, C—H...N and π–π stacking interactions in the structure.