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Tris(1H-imidazole-κN3)(dl-malato-κ3O,O′,O′′)nickel(II)

✍ Scribed by Lin, Dong-Dong ;Xu, Duan-Jun


Publisher
International Union of Crystallography
Year
2005
Tongue
English
Weight
473 KB
Volume
61
Category
Article
ISSN
1600-5368

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Tris(1H-benz­imidazole-κN3)(imino­diacet
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Single-crystal X-ray study T = 295 K Mean '(C±C) = 0.004 A Ê R factor = 0.042 wR factor = 0.111 Data-to-parameter ratio = 15.2 For details of how these key indicators were automatically derived from the article, see http://journals.iucr.org/e.

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Single-crystal X-ray study T = 295 K Mean '(C±C) = 0.003 A Ê Disorder in main residue R factor = 0.027 wR factor = 0.070 Data-to-parameter ratio = 12.4 For details of how these key indicators were automatically derived from the article, see http://journals.iucr.org/e.

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The title complex, [Ni(C 7 H 3 NO 4 )(C 6 H 5 N 3 ) 3 ], has been prepared hydrothermally. Three neutral monodentate benzotriazole ligands occupy meridional sites about the octahedrally coordinated nickel(II) cation. The remaining sites are occupied by the N and two O atoms of a tridentate pyridine-