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mer-Tris(1H-benzotriazole-κN)(pyridine-2,6-dicarboxyl­ato-κ3N,O,O′)nickel(II)

✍ Scribed by Ramadevi, Palani ;Kumaresan, Sudalaiandi ;Muir, Kenneth W.

Publisher
International Union of Crystallography
Year
2005
Tongue
English
Weight
322 KB
Volume
61
Category
Article
ISSN
1600-5368

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✦ Synopsis

The title complex, [Ni(C 7 H 3 NO 4 )(C 6 H 5 N 3 ) 3 ], has been prepared hydrothermally. Three neutral monodentate benzotriazole ligands occupy meridional sites about the octahedrally coordinated nickel(II) cation. The remaining sites are occupied by the N and two O atoms of a tridentate pyridine-2,6-dicarboxylate dianion.

📜 SIMILAR VOLUMES

Penta­aqua-1κ5O-(μ-pyridine-2,6-dicarbox
Penta­aqua-1κ5O-(μ-pyridine-2,6-dicarboxyl­ato-1κO2:2κ3O2′,N,O6)(pyridine-2,6-dicarboxyl­ato-2κ3O2,N,O6)dimanganese(II) dihydrate
✍ Liu, Ying ;Dou, Jian-Min ;Wang, Da-Qi ;Zhang, Xian-Xi ;Zhou, Lei 📂 Article 📅 2006 🏛 International Union of Crystallography 🌐 English ⚖ 302 KB

The title compound, [Mn 2 (C 7 H 3 NO 4 ) 2 (H 2 O) 5 ]Á2H 2 O, has been prepared from the hydrothermal reaction of manganese(II) chloride tetrahydrate and pyridine-2,6-dicarboxylic acid. It is isostructural with the analogous Co II , Ni II , Cu II and Zn II compounds.