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Triplet-Triplet Annihilation and Excimer Fluorescence in Poly(naphthyl methacrylate)

โœ Scribed by Somerall, A. C.; Guillet, J. E.


Book ID
126261972
Publisher
American Chemical Society
Year
1973
Tongue
English
Weight
700 KB
Volume
6
Category
Article
ISSN
0024-9297

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The triplet-triplet annihilation of the lowest-lying excited states of porphyrins and phthalocyanines has been investigated by laser flash photolysis. Spectroscopic and kinetic evtdence indicates that the lowest-lying triplet dimerizes into excimers at a rate less than diffusion controlled.

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## Abstract Tripletโ€“triplet annihilation (TTA) is studied in a wide range of fluorescent host:guest emitter systems used in organic lightโ€emitting devices (OLEDs). Strong TTA is observed in host:guest systems in which the dopant has a limited chargeโ€trapping capability. On the other hand, systems i