Triplet-Triplet-Absorption einiger carbonylhaltiger Verbindungen
✍ Scribed by M. V. Alfimov; N. Ja. Buben; V. L. Glazolev; E. S. Kujumdži; Ju. V. Pomazan; V. N. Šamšev
- Book ID
- 105181798
- Publisher
- Springer
- Year
- 1980
- Weight
- 146 KB
- Volume
- 258
- Category
- Article
- ISSN
- 0340-255X
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Biphenyl in a cooled alcoholic solution shows structured TT absorption bands, weak in the visible and strong in the UV with a maximum at 3'7OOA and en Er= 50 000 litre mole-1 cm-I. Calculations using the PPP SCF method with a large configuration interaction are done using a planar model. The influen
Triplet-triplet absorption of biphenylene was sensitized by naphthalene. A band is observed at 29 500 cm-l and is assigned to a predicted 3B& + 3B& transition. Triplet biphenylene has a lifetime of 100 psec in solution. Nonradiative processes are thought to affect mainly the first singlet state of b