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Sensitized triplet-triplet absorption of biphenylene

✍ Scribed by C. Tetreau; D. Lavalette; E.J. Land; F. Peradejordi

Publisher: Elsevier Science
Year: 1972
Tongue: English
Weight: 402 KB
Volume: 17
Category: Article
ISSN: 0009-2614
DOI: 10.1016/0009-2614(72)87065-9

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✦ Synopsis

Triplet-triplet absorption of biphenylene was sensitized by naphthalene. A band is observed at 29 500 cm-l and is assigned to a predicted 3B& + 3B& transition. Triplet biphenylene has a lifetime of 100 psec in solution. Nonradiative processes are thought to affect mainly the first singlet state of biphenylene.

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