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Triplet state radiationless transitions in polycyclic hydrocarbons

✍ Scribed by Clarke, Richard H.


Book ID
121727472
Publisher
American Institute of Physics
Year
1976
Tongue
English
Weight
919 KB
Volume
65
Category
Article
ISSN
0021-9606

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Extremely fast radiationless transition
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The decay of the lowest excited triplet state of 9,10-diazaphenanthrene (DAP) was investigated. A surprisingly high sublevel decay rate ( kv= 3.3 X 10' s-' ) in biphenyl and fluorene hosts was found at 3.0 K from the decay of a time-resolved EPR (TREPR) signal. This high decay rate was confirmed by

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**Abstractβ€”** –Triplet states of several large polycyclic aromatic hydrocarbons together with their lifetimes have been determined both in fluid solution and in the solid state using a spectrophoto‐metric technique. Excited states and lifetimes of some solid charge transfer complexes between the hy