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Radiationless transitions in alternant hydrocarbons

✍ Scribed by U. Sommer


Publisher
Elsevier Science
Year
1971
Tongue
English
Weight
201 KB
Volume
8
Category
Article
ISSN
0009-2614

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A previously derived expression for Franck-Condon factors of radiationless transitions in aromatic hydrocarbons contains a semi-empirical anharmonicity parameter. It is shown that this parameter can be calculated accurately on the basis of Morse potentials.

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The quantitative interpretation of the fluorescence quenching of anthracene in various solvents based on a recently deveIoped theory of radiationless transitions is given. It is shown that high temperature results can be expIained in terms of the Sl-+ Ta transition only\_ so there is no need to assu