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Triplet excitation of C60 and the structure of the crystal at 1.2 K

✍ Scribed by E.J.J. Groenen; O.G. Poluektov; M. Matsushita; J. Schmidt; J.H. van der Waals; G. Meijer

Publisher: Elsevier Science
Year: 1992
Tongue: English
Weight: 499 KB
Volume: 197
Category: Article
ISSN: 0009-2614
DOI: 10.1016/0009-2614(92)85775-6

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✦ Synopsis

Electron-spin-echo experiments at 95 GHz and 1.2 K reveal that the triplet excitation of a single crystal of CeO is delocalized over either a pair or a chain oft& molecules along ( 110) directions. Two distinct triplet species have been observed in a one-toone ratio which verifies the proposed 2 a0 face-centred cubic superstructure of the crystal at low temperature. The C6,, molecules on the two sublattices differ by a rotation over 60" about ( 111) directions.

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