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Triphenylphosphine-Catalyzed Formation of Functionalized 2-Aminothiophenes.

✍ Scribed by David Virieux; Anne-Francoise Guillouzic; Henri-Jean Cristau

Publisher: John Wiley and Sons
Year: 2007
Weight: 22 KB
Volume: 38
Category: Article
ISSN: 0931-7597
DOI: 10.1002/chin.200733106

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## Abstract Triphenylphosphine was used as a nucleophilic catalyst in the addition–cyclization reaction of phenyl isothiocyanate with electron‐deficient allenes. This strategy offers a new approach for the synthesis of 2‐aminothiophenes under neutral conditions. © 2007 Wiley Periodicals, Inc. Heter

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