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Trimethylsilyl group migration in the Criegee intermediate of gas-phase ozonolysis of trimethylsilylethenes

✍ Scribed by Radek Fajgar; Josef Pola

Publisher
Elsevier Science
Year
2000
Tongue
French
Weight
96 KB
Volume
41
Category
Article
ISSN
0040-4039

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✦ Synopsis

GC, GC/MS and GC/FTIR analyses of the final products of ozonolysis of trimethylsilylethene and trans-1,3bis(trimethylsilyl)ethene reveal that the ester channel of decomposition of the Criegee intermediate takes place exclusively via migration of Me 3 Si group.

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