✦ LIBER ✦

Kinetics and energetics of the criegee intermediate in the gas phase. II. The criegee intermediate in the photooxidation of formaldehyde, in alkyldioxy disproportionation and O + oxoalkane addition reactions

✍ Scribed by John T. Herron; Richard I. Martinez; Robert E. Huie

Publisher: John Wiley and Sons
Year: 1982
Tongue: English
Weight: 639 KB
Volume: 14
Category: Article
ISSN: 0538-8066
DOI: 10.1002/kin.550140303

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✦ Synopsis

Abstract

The gas‐phase kinetics and energetics of the Criegee intermediate, deduced from studies of O~3~‐alkene systems, suggest that a hydroxy‐substituted Criegee intermediate probably participates in the photooxidation of formaldehyde. In contradistinction, the existing evidence suggests that the Criegee intermediate and its isomers are probably not involved in alkyldioxy disproportionation reactions. In the case of O + oxoalkane addition reactions, the Criegee intermediate and its isomers are discussed in terms of a complex equilibrium: .

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