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Trimethylsilyl accelerated retro-Diels-Alder reaction: a quantitative measure of the .beta.-effect

✍ Scribed by Magnus, Philip; Cairns, Peter M.; Moursounidis, John

Book ID
126853327
Publisher
American Chemical Society
Year
1987
Tongue
English
Weight
391 KB
Volume
109
Category
Article
ISSN
0002-7863

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The activation and reaction volumes (βˆ†V /βˆ†V) were showing negative volumes of activation (βˆ†V Ο½ 0) whereas the others are slightly retarded (βˆ†V ΟΎ 0). From the analysis determined for the retro Diels-Alder reactions of the parent dihydrobarrelene 1a, its 2-cyano derivative 1b, the exo and of the volum